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Metallaboratranes: The M→B Dative Bond as a Ligand Activating Function in the Phosphaboration of Carbon Monosulfide

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dc.contributor.authorCrossley, Ian R
dc.contributor.authorHill, Anthony
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-08T22:18:40Z
dc.date.issued2007
dc.date.updated2015-12-08T08:18:20Z
dc.description.abstractThe reaction of Na[H2B(mt)2] (mt = methimazolyl) with [RhCl(CO)(PPh3)2] proceeds via simple metathesis to provide the complex [Rh(CO)(PPh3){H2B(mt)2}]; however, with [RhCl(CS)(PPh3)2] C,C-phosphaboration of the thiocarbonyl ligand occurs, with formation of the novel cage complex [RhH-(PPh3){η2(C,S), κ2S′, S″-SC(PPh3)BH(mt)2}].
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/31449
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Chemical bonds; Complexation; Ligands; Organometallics; Synthesis (chemical); Carbon monosulfide; Ligand activating function; Metathesis; Phosphaboration; Boron compounds
dc.titleMetallaboratranes: The M→B Dative Bond as a Ligand Activating Function in the Phosphaboration of Carbon Monosulfide
dc.typeJournal article
local.bibliographicCitation.issue16
local.bibliographicCitation.lastpage3895
local.bibliographicCitation.startpage3891
local.contributor.affiliationCrossley, Ian R, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidCrossley, Ian R, u4120782
local.contributor.authoruidHill, Anthony, u4030185
local.contributor.authoruidWillis, Anthony, u8512028
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.ariespublicationu4217927xPUB83
local.identifier.citationvolume26
local.identifier.doi10.1021/om700433q
local.identifier.scopusID2-s2.0-34547797363
local.type.statusPublished Version

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