Metallaboratranes: The M→B Dative Bond as a Ligand Activating Function in the Phosphaboration of Carbon Monosulfide

Date

2007

Authors

Crossley, Ian R
Hill, Anthony
Willis, Anthony

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

The reaction of Na[H2B(mt)2] (mt = methimazolyl) with [RhCl(CO)(PPh3)2] proceeds via simple metathesis to provide the complex [Rh(CO)(PPh3){H2B(mt)2}]; however, with [RhCl(CS)(PPh3)2] C,C-phosphaboration of the thiocarbonyl ligand occurs, with formation of the novel cage complex [RhH-(PPh3){η2(C,S), κ2S′, S″-SC(PPh3)BH(mt)2}].

Description

Keywords

Keywords: Chemical bonds; Complexation; Ligands; Organometallics; Synthesis (chemical); Carbon monosulfide; Ligand activating function; Metathesis; Phosphaboration; Boron compounds

Citation

Source

Organometallics

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/om700433q

Restricted until

2037-12-31