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Homoleptic cerium(III) and cerium(IV) nitroxide complexes: Significant stabilization of the 4+ oxidation state

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dc.contributor.authorBogart, Justin A.
dc.contributor.authorLewis, Andrea J.
dc.contributor.authorMedling, Scott
dc.contributor.authorPiro, Nicholas A.
dc.contributor.authorCarroll, Patrick J.
dc.contributor.authorBooth, Corwin H.
dc.contributor.authorSchelter, Eric J.
dc.date.accessioned2015-12-10T23:16:05Z
dc.date.issued2013
dc.date.updated2015-12-10T09:49:51Z
dc.description.abstractElectrochemical experiments performed on the complex CeIV[2- (tBuNO)py]4, where [2-(tBuNO)py]- = N-tert-butyl-N-2-pyridylnitroxide, indicate a 2.51 V stabilization of the 4+ oxidation state of Ce compared to [nBu4N] 2[Ce(NO3)6] in acetonitrile and a 2.95
dc.identifier.issn0020-1669
dc.identifier.urihttp://hdl.handle.net/1885/64912
dc.publisherAmerican Chemical Society
dc.sourceInorganic Chemistry
dc.titleHomoleptic cerium(III) and cerium(IV) nitroxide complexes: Significant stabilization of the 4+ oxidation state
dc.typeJournal article
local.bibliographicCitation.issue19
local.bibliographicCitation.lastpage11607
local.bibliographicCitation.startpage11600
local.contributor.affiliationBogart, Justin A., University of Pennsylvania
local.contributor.affiliationLewis, Andrea J., University of Pennsylvania
local.contributor.affiliationMedling, Scott, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationPiro, Nicholas A., University of Pennsylvania
local.contributor.affiliationCarroll, Patrick J., University of Pennsylvania
local.contributor.affiliationBooth, Corwin H., Lawrence Berkeley National Laboratory
local.contributor.affiliationSchelter, Eric J., University of Pennsylvania
local.contributor.authoruidMedling, Scott, u5434598
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor020406 - Surfaces and Structural Properties of Condensed Matter
local.identifier.absfor020404 - Electronic and Magnetic Properties of Condensed Matter; Superconductivity
local.identifier.absseo970102 - Expanding Knowledge in the Physical Sciences
local.identifier.ariespublicationU3488905xPUB1019
local.identifier.citationvolume52
local.identifier.doi10.1021/ic401974t
local.identifier.scopusID2-s2.0-84885120727
local.identifier.thomsonID000326319800106
local.type.statusPublished Version

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