Homoleptic cerium(III) and cerium(IV) nitroxide complexes: Significant stabilization of the 4+ oxidation state
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Bogart, Justin A.
Lewis, Andrea J.
Medling, Scott
Piro, Nicholas A.
Carroll, Patrick J.
Booth, Corwin H.
Schelter, Eric J.
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American Chemical Society
Abstract
Electrochemical experiments performed on the complex CeIV[2- (tBuNO)py]4, where [2-(tBuNO)py]- = N-tert-butyl-N-2-pyridylnitroxide, indicate a 2.51 V stabilization of the 4+ oxidation state of Ce compared to [nBu4N] 2[Ce(NO3)6] in acetonitrile and a 2.95
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Inorganic Chemistry
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2037-12-31
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