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Competitive Intramolecular Diels-Alder Reactions of bis-α,β-Unsaturated Ester Derivatives of Enzymatically Derived and Enantiopure cis -1,2-Dihydrocatechols. Enantiodivergent Synthesis of Monochiral Bicyclo[2.2.2]oct-2-enes

dc.contributor.authorBanwell, Martin
dc.contributor.authorChun, Chonhoon
dc.contributor.authorEdwards, Alison
dc.contributor.authorVogtle, Markus
dc.date.accessioned2015-12-13T23:05:59Z
dc.date.available2015-12-13T23:05:59Z
dc.date.issued2003
dc.date.updated2015-12-12T08:03:11Z
dc.description.abstractbis-Crotonate and related alpha;,β-unsaturated ester derivatives of readily available and enantiomerically pure cis-1,2-dihydrocatechols engage, upon heating in refluxing toluene, in two competitive intramolecular Diels-Alder reactions to give varying mi
dc.identifier.issn0004-9425
dc.identifier.urihttp://hdl.handle.net/1885/85806
dc.publisherCSIRO Publishing
dc.sourceAustralian Journal of Chemistry
dc.subjectKeywords: Benzene; Chromatography; Crystal structure; Derivatives; Enzymes; Esters; Single crystals; Synthesis (chemical); Toluene; X ray analysis; Competitive intramolecular Diels-Alder reaction; Enantiodivergent synthesis; Enzymatic dihydroxylation; Single crysta
dc.titleCompetitive Intramolecular Diels-Alder Reactions of bis-α,β-Unsaturated Ester Derivatives of Enzymatically Derived and Enantiopure cis -1,2-Dihydrocatechols. Enantiodivergent Synthesis of Monochiral Bicyclo[2.2.2]oct-2-enes
dc.typeJournal article
local.bibliographicCitation.issue9
local.bibliographicCitation.lastpage869
local.bibliographicCitation.startpage861
local.contributor.affiliationBanwell, Martin, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationChun, Chonhoon, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationEdwards, Alison, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationVogtle, Markus, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidBanwell, Martin, u9500594
local.contributor.authoruidChun, Chonhoon, u3326422
local.contributor.authoruidEdwards, Alison, u9900186
local.contributor.authoruidVogtle, Markus, t453
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030503 - Organic Chemical Synthesis
local.identifier.ariespublicationMigratedxPub14464
local.identifier.citationvolume56
local.identifier.doi10.1071/CH03112
local.identifier.scopusID2-s2.0-0042281892
local.type.statusPublished Version

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