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Competitive Intramolecular Diels-Alder Reactions of bis-α,β-Unsaturated Ester Derivatives of Enzymatically Derived and Enantiopure cis -1,2-Dihydrocatechols. Enantiodivergent Synthesis of Monochiral Bicyclo[2.2.2]oct-2-enes

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Date

2003

Authors

Banwell, Martin
Chun, Chonhoon
Edwards, Alison
Vogtle, Markus

Journal Title

Journal ISSN

Volume Title

Publisher

CSIRO Publishing

Abstract

bis-Crotonate and related alpha;,β-unsaturated ester derivatives of readily available and enantiomerically pure cis-1,2-dihydrocatechols engage, upon heating in refluxing toluene, in two competitive intramolecular Diels-Alder reactions to give varying mi

Description

Keywords

Keywords: Benzene; Chromatography; Crystal structure; Derivatives; Enzymes; Esters; Single crystals; Synthesis (chemical); Toluene; X ray analysis; Competitive intramolecular Diels-Alder reaction; Enantiodivergent synthesis; Enzymatic dihydroxylation; Single crysta

Citation

URI

http://hdl.handle.net/1885/85806

Collections

ANU Research Publications

Source

Australian Journal of Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1071/CH03112

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