The reversible and stereoselective N- to C-bonded rearrangement of tris(2-pyridylmethyl)-1,4,7-triazacyclononanecobalt(III)
| dc.contributor.author | Jackson, William Gregory | |
| dc.contributor.author | McKeon, Josephine A | |
| dc.contributor.author | Hockless, David | |
| dc.contributor.author | Willis, Anthony | |
| dc.date.accessioned | 2015-12-13T23:04:07Z | |
| dc.date.issued | 2006 | |
| dc.date.updated | 2015-12-12T07:53:35Z | |
| dc.description.abstract | The hexaaminecobalt(III) complex [Co(tmptacn)]3+ (tmptacn = 1,4,7-tris(2′-pyridylmethyl)-1,4,7-triazacyclononane) undergoes a novel base-catalyzed N- to C-bonded rearrangement in which a tacn nitrogen is displaced by the α-carbon which deprotonates and | |
| dc.identifier.issn | 0020-1669 | |
| dc.identifier.uri | http://hdl.handle.net/1885/85223 | |
| dc.publisher | American Chemical Society | |
| dc.source | Inorganic Chemistry | |
| dc.subject | Keywords: carbon; nitrogen; organometallic compound; tris(2 pyridylmethyl) 1,4,7 triazacyclononanecobalt(III); tris(2-pyridylmethyl)-1,4,7-triazacyclononanecobalt(III); article; catalysis; chemical structure; chemistry; conformation; kinetics; methodology; nuclear | |
| dc.title | The reversible and stereoselective N- to C-bonded rearrangement of tris(2-pyridylmethyl)-1,4,7-triazacyclononanecobalt(III) | |
| dc.type | Journal article | |
| local.bibliographicCitation.issue | 10 | |
| local.bibliographicCitation.lastpage | 4135 | |
| local.bibliographicCitation.startpage | 4119 | |
| local.contributor.affiliation | Jackson, William Gregory, University of New South Wales, ADFA | |
| local.contributor.affiliation | McKeon, Josephine A, University of New South Wales, ADFA | |
| local.contributor.affiliation | Hockless, David, College of Physical and Mathematical Sciences, ANU | |
| local.contributor.affiliation | Willis, Anthony, College of Physical and Mathematical Sciences, ANU | |
| local.contributor.authoremail | u8512028@anu.edu.au | |
| local.contributor.authoruid | Hockless, David, u930167 | |
| local.contributor.authoruid | Willis, Anthony, u8512028 | |
| local.description.embargo | 2037-12-31 | |
| local.description.notes | Imported from ARIES | |
| local.description.refereed | Yes | |
| local.identifier.absfor | 030606 - Structural Chemistry and Spectroscopy | |
| local.identifier.absfor | 030207 - Transition Metal Chemistry | |
| local.identifier.ariespublication | MigratedxPub13510 | |
| local.identifier.citationvolume | 45 | |
| local.identifier.doi | 10.1021/ic051997f | |
| local.identifier.scopusID | 2-s2.0-33646904544 | |
| local.identifier.uidSubmittedBy | Migrated | |
| local.type.status | Published Version |
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