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The reversible and stereoselective N- to C-bonded rearrangement of tris(2-pyridylmethyl)-1,4,7-triazacyclononanecobalt(III)

Date

Authors

Jackson, William Gregory

McKeon, Josephine A

Hockless, David

Willis, Anthony

Publisher

American Chemical Society

Abstract

The hexaaminecobalt(III) complex [Co(tmptacn)]3+ (tmptacn = 1,4,7-tris(2′-pyridylmethyl)-1,4,7-triazacyclononane) undergoes a novel base-catalyzed N- to C-bonded rearrangement in which a tacn nitrogen is displaced by the α-carbon which deprotonates and

Keywords

Keywords: carbon; nitrogen; organometallic compound; tris(2 pyridylmethyl) 1,4,7 triazacyclononanecobalt(III); tris(2-pyridylmethyl)-1,4,7-triazacyclononanecobalt(III); article; catalysis; chemical structure; chemistry; conformation; kinetics; methodology; nuclear

URI

http://hdl.handle.net/1885/85223

Collections

ANU Research Publications

Source

Inorganic Chemistry

Type

Journal article

DOI

10.1021/ic051997f

Restricted until

2037-12-31

Downloads

File

Description

01_Jackson_The_reversible_and_2006.pdf (422.18 KB)