The mechanism of Bu 3 SnH-mediated homolytic aromatic substitution

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dc.contributor.authorBeckwith, Athelstan (Athel)
dc.contributor.authorBowry, Vincent W
dc.contributor.authorBowman, W Russell
dc.contributor.authorMann, Emma
dc.contributor.authorParr, Jonathan
dc.contributor.authorStorey, John W
dc.date.accessioned2015-12-13T23:07:26Z
dc.date.issued2004
dc.date.updated2015-12-12T08:09:07Z
dc.description.abstractThe fate of intermediate π radicals is crucial in Bu 3SnH-mediated cyclization by homolytic aromatic substitution, for example, of bromo compound 1 via radical 2 to give oxindole 3 (AIBN = azobisisobutyronitrile). The results indicate that the mechanism
dc.identifier.issn1433-7851
dc.identifier.urihttp://hdl.handle.net/1885/86208
dc.publisherWiley-VCH Verlag GMBH
dc.sourceAngewandte Chemie International Edition
dc.subjectKeywords: Radical reactions; Bromine compounds; Free radicals; Hydrogen; Solvents; Substitution reactions; Aromatic compounds; aromatic compound; azobisisobutyronitrile; hydrogen; oxindole; polycyclic aromatic hydrocarbon; radical; solvent; tin; unclassified drug; Azo compounds; Cyclization; Radical reactions; Radicals; Reaction mechanisms
dc.titleThe mechanism of Bu 3 SnH-mediated homolytic aromatic substitution
dc.typeJournal article
local.bibliographicCitation.issue1
local.bibliographicCitation.lastpage98
local.bibliographicCitation.startpage95
local.contributor.affiliationBeckwith, Athelstan (Athel), College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBowry, Vincent W, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBowman, W Russell, Loughborough University
local.contributor.affiliationMann, Emma, Loughborough University
local.contributor.affiliationParr, Jonathan, Loughborough University
local.contributor.affiliationStorey, John W, University of New South Wales
local.contributor.authoremailrepository.admin@anu.edu.au
local.contributor.authoruidBeckwith, Athelstan (Athel), u810237
local.contributor.authoruidBowry, Vincent W, u840077
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030505 - Physical Organic Chemistry
local.identifier.ariespublicationMigratedxPub15002
local.identifier.citationvolume43
local.identifier.doi10.1002/anie.200352419
local.identifier.scopusID2-s2.0-2442630750
local.identifier.uidSubmittedByMigrated
local.type.statusPublished Version

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