The mechanism of Bu 3 SnH-mediated homolytic aromatic substitution

Date

2004

Authors

Beckwith, Athelstan (Athel)
Bowry, Vincent W
Bowman, W Russell
Mann, Emma
Parr, Jonathan
Storey, John W

Journal Title

Journal ISSN

Volume Title

Publisher

Wiley-VCH Verlag GMBH

Abstract

The fate of intermediate π radicals is crucial in Bu 3SnH-mediated cyclization by homolytic aromatic substitution, for example, of bromo compound 1 via radical 2 to give oxindole 3 (AIBN = azobisisobutyronitrile). The results indicate that the mechanism

Description

Keywords

Keywords: Radical reactions; Bromine compounds; Free radicals; Hydrogen; Solvents; Substitution reactions; Aromatic compounds; aromatic compound; azobisisobutyronitrile; hydrogen; oxindole; polycyclic aromatic hydrocarbon; radical; solvent; tin; unclassified drug; Azo compounds; Cyclization; Radical reactions; Radicals; Reaction mechanisms

Citation

Source

Angewandte Chemie International Edition

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

Restricted until

2037-12-31