The first rhodaboratrane: [RhCl(PPh 3 ){B(mt) 3 }]( Rh→B ) (mt = methimazolyl)

dc.contributor.authorCrossley, Ian R
dc.contributor.authorForeman, Mark
dc.contributor.authorHill, Anthony
dc.contributor.authorWhite, Andrew G
dc.contributor.authorWilliams, David
dc.date.accessioned2015-12-13T23:09:01Z
dc.date.available2015-12-13T23:09:01Z
dc.date.issued2005
dc.date.updated2015-12-12T08:17:23Z
dc.description.abstractThe reaction of [Rh(C6H5)Cl2(PPh 3)2] with Na[HB(mt)3] (mt = methimazolyl) provides [RhCl(PPh3){B(mt)3}](Rh→B) the first authentic example of a compound with a rhodium-boron dative bond.
dc.identifier.issn1359-7345
dc.identifier.urihttp://hdl.handle.net/1885/86827
dc.publisherRoyal Society of Chemistry
dc.sourceChemical Communications
dc.subjectKeywords: alcohol; benzene; boron derivative; dichloromethane; Lewis base; ligand; rhodaboratrane; rhodium complex; thiamazole; unclassified drug; article; chemical bond; chemical reaction; complex formation; crystal structure; electron; ligand binding; oxidation;
dc.titleThe first rhodaboratrane: [RhCl(PPh 3 ){B(mt) 3 }]( Rh→B ) (mt = methimazolyl)
dc.typeJournal article
local.bibliographicCitation.lastpage223
local.bibliographicCitation.startpage221
local.contributor.affiliationCrossley, Ian R, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationForeman, Mark, Imperial College London
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWhite, Andrew G, University of Queensland
local.contributor.affiliationWilliams, David, Imperial College London
local.contributor.authoremailu4030185@anu.edu.au
local.contributor.authoruidCrossley, Ian R, u4120782
local.contributor.authoruidHill, Anthony, u4030185
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub15859
local.identifier.citationvolume2005/2
local.identifier.doi10.1039/b413305f
local.identifier.scopusID2-s2.0-12744253495
local.identifier.uidSubmittedByMigrated
local.type.statusPublished Version

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