The first rhodaboratrane: [RhCl(PPh 3 ){B(mt) 3 }]( Rh→B ) (mt = methimazolyl)
Date
2005
Authors
Crossley, Ian R
Foreman, Mark
Hill, Anthony
White, Andrew G
Williams, David
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
The reaction of [Rh(C6H5)Cl2(PPh 3)2] with Na[HB(mt)3] (mt = methimazolyl) provides [RhCl(PPh3){B(mt)3}](Rh→B) the first authentic example of a compound with a rhodium-boron dative bond.
Description
Keywords
Keywords: alcohol; benzene; boron derivative; dichloromethane; Lewis base; ligand; rhodaboratrane; rhodium complex; thiamazole; unclassified drug; article; chemical bond; chemical reaction; complex formation; crystal structure; electron; ligand binding; oxidation;
Citation
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Source
Chemical Communications
Type
Journal article