The first rhodaboratrane: [RhCl(PPh 3 ){B(mt) 3 }]( Rh→B ) (mt = methimazolyl)

Crossley, Ian R; Foreman, Mark; Hill, Anthony; White, Andrew G; Williams, David

The first rhodaboratrane: [RhCl(PPh 3 ){B(mt) 3 }]( Rh→B ) (mt = methimazolyl)

Date

2005

Authors

Crossley, Ian R

Foreman, Mark

Hill, Anthony

White, Andrew G

Williams, David

Publisher

Royal Society of Chemistry

Abstract

The reaction of [Rh(C6H5)Cl2(PPh 3)2] with Na[HB(mt)3] (mt = methimazolyl) provides [RhCl(PPh3){B(mt)3}](Rh→B) the first authentic example of a compound with a rhodium-boron dative bond.

Keywords

Keywords: alcohol; benzene; boron derivative; dichloromethane; Lewis base; ligand; rhodaboratrane; rhodium complex; thiamazole; unclassified drug; article; chemical bond; chemical reaction; complex formation; crystal structure; electron; ligand binding; oxidation;

URI

http://hdl.handle.net/1885/86827

Collections

ANU Research Publications

Source

Chemical Communications

Type

Journal article

DOI

10.1039/b413305f

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The first rhodaboratrane: [RhCl(PPh 3 ){B(mt) 3 }]( Rh→B ) (mt = methimazolyl)

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