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Metallophilicity in annular Ru 2 M 2 derivatives of (HMB)Ru II (tpdt) versus (bis)-η 2 -dithiolate bonding in Ru 2 M derivatives of Cp*Ru III (tpdt) (HMB = η 6 -C 6 Me 6 ; Cp* = η 5 -C 5 Me 5 ; M = Cu I , Ag I,II , Au I ; tpdt = 3-thiapentane-1,5-dithiolate)

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dc.contributor.authorShin, Richard
dc.contributor.authorTan, Geok Kheng
dc.contributor.authorKoh, Lip
dc.contributor.authorVittal, Jagadese
dc.contributor.authorGoh, Lai Yoong
dc.contributor.authorWebster, Richard
dc.date.accessioned2015-12-13T22:34:29Z
dc.date.issued2005
dc.date.updated2015-12-11T09:21:32Z
dc.description.abstractThe reaction of [(HMB)RuII(η3-tpdt)] (1: HMB = η6-C6Me6; tpdt = S(CH2CH 2S-)2) with [Cu(MeCN)4]PF 6, AgPF6, and (PPh3)AuCl gave the annular species [{(HMB)RuII(μ3-η1: η1:η3-tpdt)}2(M)2] 2+ [3: M = CuI; 3A: (M)2 = CuI, CuI(MeCN); 4: M = AgI ; 6: M =
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/76145
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Biochemistry; Chemical bonds; Complexation; Crystal structure; Derivatives; Glass fibers; Helium; Nuclear magnetic resonance spectroscopy; Oxidation; Paramagnetic resonance; Reaction kinetics; Ligands; Metallophilicity; Thermal properties; X-ray structure
dc.titleMetallophilicity in annular Ru 2 M 2 derivatives of (HMB)Ru II (tpdt) versus (bis)-η 2 -dithiolate bonding in Ru 2 M derivatives of Cp*Ru III (tpdt) (HMB = η 6 -C 6 Me 6 ; Cp* = η 5 -C 5 Me 5 ; M = Cu I , Ag I,II , Au I ; tpdt = 3-thiapentane-1,5-dithiolate)
dc.typeJournal article
local.bibliographicCitation.issue4
local.bibliographicCitation.lastpage551
local.bibliographicCitation.startpage539
local.contributor.affiliationShin, Richard, National University of Singapore
local.contributor.affiliationTan, Geok Kheng, National University of Singapore
local.contributor.affiliationKoh, Lip, National University of Singapore
local.contributor.affiliationVittal, Jagadese, National University of Singapore
local.contributor.affiliationGoh, Lai Yoong, National University of Singapore
local.contributor.affiliationWebster, Richard, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidWebster, Richard, u9902026
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub5026
local.identifier.citationvolume24
local.identifier.doi10.1021/om0491950
local.identifier.scopusID2-s2.0-14644404329
local.type.statusPublished Version

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