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Experimental evidence for competitive N-O and O-C bond homolysis in gas-phase alkoxyamines

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dc.contributor.authorMarshall, David L
dc.contributor.authorGryn'ova, Ganna
dc.contributor.authorCoote, Michelle
dc.contributor.authorBarker, Philip J.
dc.contributor.authorBlanksby, Stephen James
dc.date.accessioned2015-12-10T23:13:12Z
dc.date.issued2015
dc.date.updated2015-12-10T09:37:08Z
dc.description.abstractThe extensive use of alkoxyamines in controlled radical polymerisation and polymer stabilisation is based on rapid cycling between the alkoxyamine (R1R2NOR3) and a stable nitroxyl radical (R1R2NO•) via homolysis of the labile OC bond. Competing homolysi
dc.identifier.issn1387-3806
dc.identifier.urihttp://hdl.handle.net/1885/64313
dc.publisherElsevier
dc.sourceInternational Journal of Mass Spectrometry
dc.titleExperimental evidence for competitive N-O and O-C bond homolysis in gas-phase alkoxyamines
dc.typeJournal article
local.bibliographicCitation.lastpage47
local.bibliographicCitation.startpage38
local.contributor.affiliationMarshall, David L, University of Wollongong
local.contributor.affiliationGryn'ova, Ganna, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCoote, Michelle, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationBarker, Philip J., Bluescope Steel Research
local.contributor.affiliationBlanksby, Stephen James, University of Wollongong
local.contributor.authoruidGryn'ova, Ganna, u4768988
local.contributor.authoruidCoote, Michelle, u4031074
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030701 - Quantum Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu4005981xPUB915
local.identifier.citationvolume378
local.identifier.doi10.1016/j.ijms.2014.06.030
local.identifier.scopusID2-s2.0-84904518049
local.type.statusPublished Version

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