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Experimental evidence for competitive N-O and O-C bond homolysis in gas-phase alkoxyamines

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Date

2015

Authors

Marshall, David L
Gryn'ova, Ganna
Coote, Michelle
Barker, Philip J.
Blanksby, Stephen James

Journal Title

Journal ISSN

Volume Title

Publisher

Elsevier

Abstract

The extensive use of alkoxyamines in controlled radical polymerisation and polymer stabilisation is based on rapid cycling between the alkoxyamine (R1R2NOR3) and a stable nitroxyl radical (R1R2NO•) via homolysis of the labile OC bond. Competing homolysi

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Keywords

Citation

URI

http://hdl.handle.net/1885/64313

Collections

ANU Research Publications

Source

International Journal of Mass Spectrometry

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1016/j.ijms.2014.06.030

Restricted until

2037-12-31

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