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Noninnocent Ligand Behavior in Diruthenium Complexes Containing a 1,3-Diethynylbenzene Bridge.

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dc.contributor.authorFox, Mark A
dc.contributor.authorFarmer, Julian D
dc.contributor.authorRoberts, Rachel
dc.contributor.authorLow, Paul J
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-10T22:40:36Z
dc.date.issued2009
dc.date.updated2016-02-24T10:43:06Z
dc.description.abstractThe electronic structures of 1,3-{trans-Cl(dppe)2RuC≡C} 2C6H4 (3) and 1, 3 - {Cp*(dppe) RuC≡C}2C6H4 (4) in their available redox states have been investigated using a combination of UV- vis-near-IR and IR spectroscopy and computational methods. In con
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/57520
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Absorption band; Acetylides; Charge transfer transitions; Diruthenium complex; Electronic transition; IR spectroscopy; Low energies; Metal oxidation; Mixed valence systems; Near-IR; Non-innocent ligands; Oxidation process; Redox state; Ruthenium complexes
dc.titleNoninnocent Ligand Behavior in Diruthenium Complexes Containing a 1,3-Diethynylbenzene Bridge.
dc.typeJournal article
local.bibliographicCitation.issue17
local.bibliographicCitation.lastpage5269
local.bibliographicCitation.startpage5266
local.contributor.affiliationFox, Mark A, University of Durham
local.contributor.affiliationFarmer, Julian D, University of Durham
local.contributor.affiliationRoberts, Rachel, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLow, Paul J, University of Durham
local.contributor.authoruidRoberts, Rachel, u4429092
local.contributor.authoruidHumphrey, Mark, u9400918
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationu4217927xPUB404
local.identifier.citationvolume28
local.identifier.doi10.1021/om900200n
local.identifier.scopusID2-s2.0-69949141134
local.identifier.thomsonID000269424200048
local.type.statusPublished Version

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