Noninnocent Ligand Behavior in Diruthenium Complexes Containing a 1,3-Diethynylbenzene Bridge.

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Fox, Mark A
Farmer, Julian D
Roberts, Rachel
Low, Paul J
Humphrey, Mark

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American Chemical Society

Abstract

The electronic structures of 1,3-{trans-Cl(dppe)2RuC≡C} 2C6H4 (3) and 1, 3 - {Cp*(dppe) RuC≡C}2C6H4 (4) in their available redox states have been investigated using a combination of UV- vis-near-IR and IR spectroscopy and computational methods. In con

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Organometallics

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2037-12-31