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Mixed-metal cluster chemistry: 32. Synthesis, structure, and reactivity of a trimetallic molybdenum-iridium carbonyl cluster possessing a μ 3 -η 2 -benzyne ligand

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dc.contributor.authorRandles , Michael
dc.contributor.authorGupta, Vivek
dc.contributor.authorSimpson, Peter
dc.contributor.authorMoxey, Graeme
dc.contributor.authorCriddle, Alan
dc.contributor.authorStranger, Robert
dc.contributor.authorCifuentes, Marie
dc.contributor.authorHumphrey, Mark
dc.date.accessioned2015-12-10T23:02:03Z
dc.date.issued2013
dc.date.updated2016-02-24T10:25:28Z
dc.description.abstractThe reaction of Mo2Ir2(μ-CO)3(CO) 7(η5-C5H5)2 and Ir(CCCH2OH)(CO)(PPh3)3 in refluxing toluene gives the molybdenum-iridium cluster MoIr2(μ3- η2-C6H4)(μ-PPh2)(μ-CO) 2(CO)4(η5-C5H5) (1) in low yield. Mo2Ir2(μ-CO)3(CO) 6(PPh3)(η5-C5H5) 2 (2) is a po
dc.identifier.issn0277-5387
dc.identifier.urihttp://hdl.handle.net/1885/61842
dc.publisherPergamon-Elsevier Ltd
dc.sourcePolyhedron
dc.subjectKeywords: Carbonyl; Cluster; Cyclopentadienyl; Phosphine; X-ray structure
dc.titleMixed-metal cluster chemistry: 32. Synthesis, structure, and reactivity of a trimetallic molybdenum-iridium carbonyl cluster possessing a μ 3 -η 2 -benzyne ligand
dc.typeJournal article
local.bibliographicCitation.lastpage962
local.bibliographicCitation.startpage957
local.contributor.affiliationRandles , Michael , College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationGupta, Vivek, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSimpson, Peter, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationMoxey, Graeme, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCriddle, Alan, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationStranger, Robert, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCifuentes, Marie, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHumphrey, Mark, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidRandles , Michael , u3956935
local.contributor.authoruidGupta, Vivek, u4309605
local.contributor.authoruidSimpson, Peter, u4906970
local.contributor.authoruidMoxey, Graeme, u5200340
local.contributor.authoruidCriddle, Alan, u4540237
local.contributor.authoruidStranger, Robert, u8708796
local.contributor.authoruidCifuentes, Marie, u9410034
local.contributor.authoruidHumphrey, Mark, u9400918
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu4005981xPUB644
local.identifier.citationvolume52
local.identifier.doi10.1016/j.poly.2012.07.018
local.identifier.scopusID2-s2.0-84875409554
local.identifier.thomsonID000318747100117
local.type.statusPublished Version

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