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Mixed-metal cluster chemistry: 32. Synthesis, structure, and reactivity of a trimetallic molybdenum-iridium carbonyl cluster possessing a μ 3 -η 2 -benzyne ligand

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Date

2013

Authors

Randles , Michael
Gupta, Vivek
Simpson, Peter
Moxey, Graeme
Criddle, Alan
Stranger, Robert
Cifuentes, Marie
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

Pergamon-Elsevier Ltd

Abstract

The reaction of Mo2Ir2(μ-CO)3(CO) 7(η5-C5H5)2 and Ir(CCCH2OH)(CO)(PPh3)3 in refluxing toluene gives the molybdenum-iridium cluster MoIr2(μ3- η2-C6H4)(μ-PPh2)(μ-CO) 2(CO)4(η5-C5H5) (1) in low yield. Mo2Ir2(μ-CO)3(CO) 6(PPh3)(η5-C5H5) 2 (2) is a po

Description

Keywords

Keywords: Carbonyl; Cluster; Cyclopentadienyl; Phosphine; X-ray structure

Citation

URI

http://hdl.handle.net/1885/61842

Collections

ANU Research Publications

Source

Polyhedron

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1016/j.poly.2012.07.018

Restricted until

2037-12-31

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01_Randles _Mixed-metal_cluster_chemistry:_2013.pdf (517.65 KB)

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