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Synthesis and Reactivity of Phosphinocarbyne Complexes

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dc.contributor.authorColebatch, Annie
dc.contributor.authorHill, Anthony
dc.contributor.authorSharma, Manab
dc.date.accessioned2015-12-10T23:11:04Z
dc.date.issued2015
dc.date.updated2019-11-25T07:48:34Z
dc.description.abstractThe successive treatment of [W(≡CBr)(CO)<inf>2</inf>(Tp∗)] (Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with nBuLi and ClPPh<inf>2</inf> affords the phosphinocarbyne complex [W(≡CPPh<inf>2</inf>)(CO)<inf>2</inf>(Tp∗)] (1), DFT interrogation
dc.identifier.issn0276-7333
dc.identifier.urihttp://hdl.handle.net/1885/63660
dc.publisherAmerican Chemical Society
dc.sourceOrganometallics
dc.subjectKeywords: Carbon; Dichloromethane; Phosphorus; Sulfur; Synthesis (chemical); Tungsten; Diethyl ethers; Dimethylsulfide; Electrophiles; Electrophilic attack; Electrophilic reagents; Iodomethane; Multiple bonds; Phosphorus atom; Tungsten compounds
dc.titleSynthesis and Reactivity of Phosphinocarbyne Complexes
dc.typeJournal article
local.bibliographicCitation.issue11
local.bibliographicCitation.lastpage2182
local.bibliographicCitation.startpage2165
local.contributor.affiliationColebatch, Annie, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationSharma, Manab, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidColebatch, Annie, u4213195
local.contributor.authoruidHill, Anthony, u4030185
local.contributor.authoruidSharma, Manab, u4939765
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationU4217927xPUB833
local.identifier.citationvolume34
local.identifier.doi10.1021/om500833n
local.identifier.scopusID2-s2.0-84931273800
local.identifier.thomsonID000356841800019
local.type.statusPublished Version

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