Synthesis and Reactivity of Phosphinocarbyne Complexes
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Colebatch, Annie
Hill, Anthony
Sharma, Manab
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American Chemical Society
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The successive treatment of [W(≡CBr)(CO)<inf>2</inf>(Tp∗)] (Tp∗ = hydrotris(3,5-dimethylpyrazol-1-yl)borate) with nBuLi and ClPPh<inf>2</inf> affords the phosphinocarbyne complex [W(≡CPPh<inf>2</inf>)(CO)<inf>2</inf>(Tp∗)] (1), DFT interrogation
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Organometallics
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2037-12-31
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