A mercury bis(tricarbido) complex: [Hg{C≡C�C≡W(CO) 2 Tp} 2- (dmso) 4 ](dmso) 2 (Tp = hydrotrispyrazolylborate)

dc.contributor.authorDewhurst, Rian
dc.contributor.authorHill, Anthony
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-13T23:08:58Z
dc.date.available2015-12-13T23:08:58Z
dc.date.issued2004
dc.date.updated2015-12-12T08:16:52Z
dc.description.abstractFluoride mediated desilylation of the propargylidyne complex [W(≡C-C≡CSiMe3)(CO)2{HB(pz)3)] (pz = pyrazol-1-yl) in the presence of mercury(II) chloride provides the novel bis(tricarbido)complex [Hg{C≡C-C≡W(CO)2(HB(pz)3}} 2], which was structurally
dc.identifier.issn1359-7345
dc.identifier.urihttp://hdl.handle.net/1885/86802
dc.publisherRoyal Society of Chemistry
dc.sourceChemical Communications
dc.subjectKeywords: benzyl thiocyanate; dimethyl sulfoxide; hydrotrispyrazolylborate; mercury bis(tricarbido) complex; mercury chloride; mercury derivative; propargylidyne complex; unclassified drug; article; complex formation; crystal structure; desilylation; geometry; spec
dc.titleA mercury bis(tricarbido) complex: [Hg{C≡C�C≡W(CO) 2 Tp} 2- (dmso) 4 ](dmso) 2 (Tp = hydrotrispyrazolylborate)
dc.typeJournal article
local.bibliographicCitation.issue24
local.bibliographicCitation.lastpage2827
local.bibliographicCitation.startpage2826
local.contributor.affiliationDewhurst, Rian, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.authoremailu4030185@anu.edu.au
local.contributor.authoruidDewhurst, Rian, u4040731
local.contributor.authoruidHill, Anthony, u4030185
local.contributor.authoruidWillis, Anthony, u8512028
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030207 - Transition Metal Chemistry
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub15806
local.identifier.doi10.1039/b412972e
local.identifier.scopusID2-s2.0-11244269418
local.identifier.uidSubmittedByMigrated
local.type.statusPublished Version

Downloads

Back to topicon-arrow-up-solid
 
APRU
IARU
 
edX
Group of Eight Member

Acknowledgement of Country

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.


Contact ANUCopyrightDisclaimerPrivacyFreedom of Information

+61 2 6125 5111 The Australian National University, Canberra

TEQSA Provider ID: PRV12002 (Australian University) CRICOS Provider Code: 00120C ABN: 52 234 063 906