A mercury bis(tricarbido) complex: [Hg{C≡C�C≡W(CO) 2 Tp} 2- (dmso) 4 ](dmso) 2 (Tp = hydrotrispyrazolylborate)
Date
2004
Authors
Dewhurst, Rian
Hill, Anthony
Willis, Anthony
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
Fluoride mediated desilylation of the propargylidyne complex [W(≡C-C≡CSiMe3)(CO)2{HB(pz)3)] (pz = pyrazol-1-yl) in the presence of mercury(II) chloride provides the novel bis(tricarbido)complex [Hg{C≡C-C≡W(CO)2(HB(pz)3}} 2], which was structurally
Description
Keywords
Keywords: benzyl thiocyanate; dimethyl sulfoxide; hydrotrispyrazolylborate; mercury bis(tricarbido) complex; mercury chloride; mercury derivative; propargylidyne complex; unclassified drug; article; complex formation; crystal structure; desilylation; geometry; spec
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Source
Chemical Communications
Type
Journal article