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Binuclear intermediates in oxidation reactions: [{Me 3 SiC≡C)Me 2 (bipy)Pt-PtMe 2 (bipy)] + in the Oxidation of Pt II Me 2 (bipy) (bipy = 2,2'-Bipyridine) by IPh(C≡CSiMe 3 )(OTf) (OTf = Triflate)

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Date

2009

Authors

Canty, Allan
Gardiner, Michael G
Jones, Roderick C.
Rodemann, Thomas
Sharma, Manab

Journal Title

Journal ISSN

Volume Title

Publisher

American Chemical Society

Abstract

(Chemical Equation Presented) A study of the reaction of PtMe 2(bipy) with IPh(C≡CSiMe3)(OTf) at low temperature in acetone, leading to detection of the Pt-Pt-bonded cation [Pt 2Me4(C≡CSiMe3)(bipy)2]+, an intermediate in the oxidation of PtII to PtIV,

Description

Keywords

Keywords: Alkynylplatinum; Bipyridine; Chemical equations; Donor ligands; Low temperatures; Oxidation reactions; Triflate; Acetone; Oxidation; Positive ions; Silicon carbide; Sugar (sucrose); Platinum; benzofuran derivative; bipyridine derivative; inorganic compoun

Citation

URI

http://hdl.handle.net/1885/61738

Collections

ANU Research Publications

Source

Journal of the American Chemical Society

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

10.1021/ja902799u

Restricted until

2037-12-31

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01_Canty_Binuclear_intermediates_in_2009.pdf (133.04 KB)

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