Binuclear intermediates in oxidation reactions: [{Me 3 SiC≡C)Me 2 (bipy)Pt-PtMe 2 (bipy)] + in the Oxidation of Pt II Me 2 (bipy) (bipy = 2,2'-Bipyridine) by IPh(C≡CSiMe 3 )(OTf) (OTf = Triflate)
Date
2009
Authors
Canty, Allan
Gardiner, Michael G
Jones, Roderick C.
Rodemann, Thomas
Sharma, Manab
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American Chemical Society
Abstract
(Chemical Equation Presented) A study of the reaction of PtMe 2(bipy) with IPh(C≡CSiMe3)(OTf) at low temperature in acetone, leading to detection of the Pt-Pt-bonded cation [Pt 2Me4(C≡CSiMe3)(bipy)2]+, an intermediate in the oxidation of PtII to PtIV,
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Keywords: Alkynylplatinum; Bipyridine; Chemical equations; Donor ligands; Low temperatures; Oxidation reactions; Triflate; Acetone; Oxidation; Positive ions; Silicon carbide; Sugar (sucrose); Platinum; benzofuran derivative; bipyridine derivative; inorganic compoun
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Journal of the American Chemical Society
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Journal article
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2037-12-31
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