Binuclear intermediates in oxidation reactions: [{Me 3 SiC≡C)Me 2 (bipy)Pt-PtMe 2 (bipy)] + in the Oxidation of Pt II Me 2 (bipy) (bipy = 2,2'-Bipyridine) by IPh(C≡CSiMe 3 )(OTf) (OTf = Triflate)

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dc.contributor.authorCanty, Allan
dc.contributor.authorGardiner, Michael G
dc.contributor.authorJones, Roderick C.
dc.contributor.authorRodemann, Thomas
dc.contributor.authorSharma, Manab
dc.date.accessioned2015-12-10T23:01:46Z
dc.date.issued2009
dc.date.updated2016-02-24T10:44:36Z
dc.description.abstract(Chemical Equation Presented) A study of the reaction of PtMe 2(bipy) with IPh(C≡CSiMe3)(OTf) at low temperature in acetone, leading to detection of the Pt-Pt-bonded cation [Pt 2Me4(C≡CSiMe3)(bipy)2]+, an intermediate in the oxidation of PtII to PtIV,
dc.identifier.issn0002-7863
dc.identifier.urihttp://hdl.handle.net/1885/61738
dc.publisherAmerican Chemical Society
dc.sourceJournal of the American Chemical Society
dc.subjectKeywords: Alkynylplatinum; Bipyridine; Chemical equations; Donor ligands; Low temperatures; Oxidation reactions; Triflate; Acetone; Oxidation; Positive ions; Silicon carbide; Sugar (sucrose); Platinum; benzofuran derivative; bipyridine derivative; inorganic compoun
dc.titleBinuclear intermediates in oxidation reactions: [{Me 3 SiC≡C)Me 2 (bipy)Pt-PtMe 2 (bipy)] + in the Oxidation of Pt II Me 2 (bipy) (bipy = 2,2'-Bipyridine) by IPh(C≡CSiMe 3 )(OTf) (OTf = Triflate)
dc.typeJournal article
local.bibliographicCitation.issue21
local.bibliographicCitation.lastpage7237
local.bibliographicCitation.startpage7236
local.contributor.affiliationCanty, Allan, University of Tasmania
local.contributor.affiliationGardiner, Michael G, University of Tasmania
local.contributor.affiliationJones, Roderick C., University of Tasmania
local.contributor.affiliationRodemann, Thomas, University of Tasmania
local.contributor.affiliationSharma, Manab, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidSharma, Manab, u4939765
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationU4217927xPUB635
local.identifier.citationvolume131
local.identifier.doi10.1021/ja902799u
local.identifier.scopusID2-s2.0-67650511260
local.identifier.thomsonID000266484900016
local.type.statusPublished Version

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