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The application of a monolithic triphenylphosphine reagent for conducting Ramirezgem-dibromoolefination reactions in flow

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dc.contributor.authorRoper, Kimberley A
dc.contributor.authorBerry, Malcolm B
dc.contributor.authorLey, Steven V
dc.date.accessioned2016-03-21T22:56:31Z
dc.date.available2016-03-21T22:56:31Z
dc.date.issued2013-09-02
dc.description.abstractThe application of a monolithic form of triphenylphosphine to the Ramirez gem-dibromoolefination reaction using flow chemistry techniques is reported. A variety of gem-dibromides were synthesised in high purity and excellent yield following only removal of solvent and no further off-line purification. It is also possible to perform the Appel reaction using the same monolith and the relationship between the mechanisms of the two reactions is discussed.en_AU
dc.description.sponsorshipWe would like to thank the EPSRC and GlaxoSmithKline (Stevenage) for studentship support (KAR) and the BP 1702 Professorship (SVL) for financial support.en_AU
dc.identifier.issn1860-5397en_AU
dc.identifier.urihttp://hdl.handle.net/1885/100842
dc.publisherBeilstein-Instituten_AU
dc.rights© 2013 Roper et al; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/2.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (http://www.beilstein-journals.org/bjoc)en_AU
dc.sourceBeilstein Journal of Organic Chemistryen_AU
dc.subjectramirez gem-dibromoolefination reactionen_AU
dc.subjectbrominationen_AU
dc.subjectflow chemistryen_AU
dc.subjectsolid-supported reagenten_AU
dc.subjecttriphenylphosphine monolithen_AU
dc.titleThe application of a monolithic triphenylphosphine reagent for conducting Ramirezgem-dibromoolefination reactions in flowen_AU
dc.typeJournal articleen_AU
dcterms.accessRightsOpen Accessen_AU
local.bibliographicCitation.lastpage1790en_AU
local.bibliographicCitation.startpage1781en_AU
local.contributor.affiliationRoper, Kimberley, College of Physical and Mathematical Sciences, CPMS Research School of Chemistry, RSC General, The Australian National Universityen_AU
local.contributor.affiliationBerry, Malcolm B., GlaxoSmithKline, United Kingdomen_AU
local.contributor.affiliationLey, Steven V., University of Cambridge, United Kingdomen_AU
local.contributor.authoruidu5424041en_AU
local.description.notesImported from ARIESen_AU
local.identifier.absfor030503en_AU
local.identifier.absseo970103en_AU
local.identifier.ariespublicationu4005981xPUB787en_AU
local.identifier.citationvolume9en_AU
local.identifier.doi10.3762/bjoc.9.207en_AU
local.identifier.essn1860-5397en_AU
local.publisher.urlhttp://www.beilstein-institut.de/en/homeen_AU
local.type.statusPublished Versionen_AU

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