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The application of a monolithic triphenylphosphine reagent for conducting Ramirezgem-dibromoolefination reactions in flow

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Date

2013-09-02

Authors

Roper, Kimberley A
Berry, Malcolm B
Ley, Steven V

Journal Title

Journal ISSN

Volume Title

Publisher

Beilstein-Institut

Abstract

The application of a monolithic form of triphenylphosphine to the Ramirez gem-dibromoolefination reaction using flow chemistry techniques is reported. A variety of gem-dibromides were synthesised in high purity and excellent yield following only removal of solvent and no further off-line purification. It is also possible to perform the Appel reaction using the same monolith and the relationship between the mechanisms of the two reactions is discussed.

Description

Keywords

ramirez gem-dibromoolefination reaction, bromination, flow chemistry, solid-supported reagent, triphenylphosphine monolith

Citation

URI

http://hdl.handle.net/1885/100842

Collections

ANU Research Publications

Source

Beilstein Journal of Organic Chemistry

Type

Journal article

Book Title

Entity type

Access Statement

Open Access

License Rights

DOI

10.3762/bjoc.9.207

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