Formation of metallaboratranes: the missing link. The first iridaboratranes, [IrH(CO)(PPh 3 ){ κ 3 - B,S,S -B(mt) 2 R}]( Ir→B ) (mt = methimazolyl, R = mt, H)
| dc.contributor.author | Crossley, Ian R | |
| dc.contributor.author | Hill, Anthony | |
| dc.contributor.author | Willis, Anthony | |
| dc.date.accessioned | 2015-12-13T22:55:11Z | |
| dc.date.issued | 2005 | |
| dc.date.updated | 2015-12-11T11:08:51Z | |
| dc.description.abstract | The reaction of Vaska's complex with 1 equiv of Na[HB(mt)3] or Na[H2(mt)2] (mt = methimazolyl) affords the iridaboratranes [IrH(CO)(PPh3){k3-B,S,S′-B(mt) 2R}](IrI→B) (R = mt, H), the first examples of metallaboratranes in which the transannular metal- | |
| dc.identifier.issn | 0276-7333 | |
| dc.identifier.uri | http://hdl.handle.net/1885/82425 | |
| dc.publisher | American Chemical Society | |
| dc.source | Organometallics | |
| dc.subject | Keywords: Boron; Chemical bonds; Complexation; Crystals; Electron energy levels; Iridium compounds; Molecular structure; Nuclear magnetic resonance; Sodium compounds; Carbonyl ligands; Electronic configurations; Metallaboratranes; Volume electrons; Organometallics | |
| dc.title | Formation of metallaboratranes: the missing link. The first iridaboratranes, [IrH(CO)(PPh 3 ){ κ 3 - B,S,S -B(mt) 2 R}]( Ir→B ) (mt = methimazolyl, R = mt, H) | |
| dc.type | Journal article | |
| local.bibliographicCitation.issue | 6 | |
| local.bibliographicCitation.lastpage | 1064 | |
| local.bibliographicCitation.startpage | 1062 | |
| local.contributor.affiliation | Crossley, Ian R, College of Physical and Mathematical Sciences, ANU | |
| local.contributor.affiliation | Hill, Anthony, College of Physical and Mathematical Sciences, ANU | |
| local.contributor.affiliation | Willis, Anthony, College of Physical and Mathematical Sciences, ANU | |
| local.contributor.authoremail | u4030185@anu.edu.au | |
| local.contributor.authoruid | Crossley, Ian R, u4120782 | |
| local.contributor.authoruid | Hill, Anthony, u4030185 | |
| local.contributor.authoruid | Willis, Anthony, u8512028 | |
| local.description.embargo | 2037-12-31 | |
| local.description.notes | Imported from ARIES | |
| local.description.refereed | Yes | |
| local.identifier.absfor | 039904 - Organometallic Chemistry | |
| local.identifier.ariespublication | MigratedxPub10681 | |
| local.identifier.citationvolume | 24 | |
| local.identifier.doi | 10.1021/om040128f | |
| local.identifier.scopusID | 2-s2.0-15944403570 | |
| local.identifier.uidSubmittedBy | Migrated | |
| local.type.status | Published Version |
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