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Formation of metallaboratranes: the missing link. The first iridaboratranes, [IrH(CO)(PPh 3 ){ κ 3 - B,S,S -B(mt) 2 R}]( Ir→B ) (mt = methimazolyl, R = mt, H)

Date

Authors

Crossley, Ian R

Hill, Anthony

Willis, Anthony

Publisher

American Chemical Society

Abstract

The reaction of Vaska's complex with 1 equiv of Na[HB(mt)3] or Na[H2(mt)2] (mt = methimazolyl) affords the iridaboratranes [IrH(CO)(PPh3){k3-B,S,S′-B(mt) 2R}](IrI→B) (R = mt, H), the first examples of metallaboratranes in which the transannular metal-

Keywords

Keywords: Boron; Chemical bonds; Complexation; Crystals; Electron energy levels; Iridium compounds; Molecular structure; Nuclear magnetic resonance; Sodium compounds; Carbonyl ligands; Electronic configurations; Metallaboratranes; Volume electrons; Organometallics

URI

http://hdl.handle.net/1885/82425

Collections

ANU Research Publications

Source

Organometallics

Type

Journal article

DOI

10.1021/om040128f

Restricted until

2037-12-31

Downloads

File

Description

01_Crossley_Formation_of_2005.pdf (89.71 KB)