Di(Carbido)Tetracosa(Carbonyl)-Decaruthenate(2-) Salts
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Bruce, Michael
Castro, Aurora
Humphrey, Paul A
Maitlis, Peter
Zaitseva, Natahsa N.
Viau, Lydie
Humphrey, Mark
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John Wiley & Sons Inc
Abstract
For the metal ruthenium, many examples of clusters with different nuclearity are known. The Ru10C2 cluster is formed by edge sharing of two Ru6C clusters. This chapter describes a synthesis of the decanuclear anion [Ru10C2(CO)24]2- from Ru3(CO)12 and calcium carbide in up to 50% yield. The chapter discusses the procedures and properties of calcium di(carbido)tetracosa(carbonyl) decaruthenium(2-) and BIS(triphenylphosphoranylidene)ammonium di (carbido)tetracosa(carbonyl)decaruthenium(2-).
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Inorganic Syntheses, Vol. 36
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Restricted until
2037-12-31
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