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Di(Carbido)Tetracosa(Carbonyl)-Decaruthenate(2-) Salts

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Date

2014

Authors

Bruce, Michael
Castro, Aurora
Humphrey, Paul A
Maitlis, Peter
Zaitseva, Natahsa N.
Viau, Lydie
Humphrey, Mark

Journal Title

Journal ISSN

Volume Title

Publisher

John Wiley & Sons Inc

Abstract

For the metal ruthenium, many examples of clusters with different nuclearity are known. The Ru10C2 cluster is formed by edge sharing of two Ru6C clusters. This chapter describes a synthesis of the decanuclear anion [Ru10C2(CO)24]2- from Ru3(CO)12 and calcium carbide in up to 50% yield. The chapter discusses the procedures and properties of calcium di(carbido)tetracosa(carbonyl) decaruthenium(2-) and BIS(triphenylphosphoranylidene)ammonium di (carbido)tetracosa(carbonyl)decaruthenium(2-).

Description

Keywords

Citation

URI

http://hdl.handle.net/1885/29356

Collections

ANU Research Publications

Source

Type

Book chapter

Book Title

Inorganic Syntheses, Vol. 36

Entity type

Access Statement

License Rights

DOI

10.1002/9781118744994.ch23

Restricted until

2037-12-31

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01_Bruce_Di(Carbido)Tetracosa(Carbonyl)-_2014.pdf (5.97 MB)

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