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Tuning the Laplaza-Cummins 3-coordinate M[N(R)Ph] 3 catalyst to activate and cleave CO 2

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dc.contributor.authorBrookes, Nigel J
dc.contributor.authorAriafard, Alireza
dc.contributor.authorStranger, Robert
dc.contributor.authorYates, Brian F
dc.date.accessioned2015-12-10T22:51:22Z
dc.date.issued2011
dc.date.updated2016-02-24T10:24:18Z
dc.description.abstractThe Laplaza-Cummins catalyst L3Mo (L = N(R)Ar), is experimentally inactive towards carbon dioxide. Previous theoretical analysis identified the cause for this inactivity and suggested that a switch to a d2 transition metal may induce activity towards the
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/1885/59015
dc.publisherRoyal Society of Chemistry
dc.sourceDalton Transactions
dc.subjectKeywords: C-O cleavage; Central metals; Density functionals; Dinuclear; Mixed-metals; Spin crossings; Triamides; Carbon dioxide; Catalysts; Molybdenum; Tantalum; Transition metals; Niobium; carbon dioxide; coordination compound; metal; niobium; tantalum; vanadium;
dc.titleTuning the Laplaza-Cummins 3-coordinate M[N(R)Ph] 3 catalyst to activate and cleave CO 2
dc.typeJournal article
local.bibliographicCitation.issue20
local.bibliographicCitation.lastpage5578
local.bibliographicCitation.startpage5569
local.contributor.affiliationBrookes, Nigel J, University of Tasmania
local.contributor.affiliationAriafard, Alireza, Islamic Azad University
local.contributor.affiliationStranger, Robert, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationYates, Brian F, University of Tasmania
local.contributor.authoruidStranger, Robert, u8708796
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030701 - Quantum Chemistry
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu4005981xPUB469
local.identifier.citationvolume40
local.identifier.doi10.1039/c1dt10026b
local.identifier.scopusID2-s2.0-79955605877
local.identifier.thomsonID000290161900021
local.type.statusPublished Version

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