Tuning the Laplaza-Cummins 3-coordinate M[N(R)Ph] 3 catalyst to activate and cleave CO 2
| dc.contributor.author | Brookes, Nigel J | |
| dc.contributor.author | Ariafard, Alireza | |
| dc.contributor.author | Stranger, Robert | |
| dc.contributor.author | Yates, Brian F | |
| dc.date.accessioned | 2015-12-10T22:51:22Z | |
| dc.date.issued | 2011 | |
| dc.date.updated | 2016-02-24T10:24:18Z | |
| dc.description.abstract | The Laplaza-Cummins catalyst L3Mo (L = N(R)Ar), is experimentally inactive towards carbon dioxide. Previous theoretical analysis identified the cause for this inactivity and suggested that a switch to a d2 transition metal may induce activity towards the | |
| dc.identifier.issn | 1477-9226 | |
| dc.identifier.uri | http://hdl.handle.net/1885/59015 | |
| dc.publisher | Royal Society of Chemistry | |
| dc.source | Dalton Transactions | |
| dc.subject | Keywords: C-O cleavage; Central metals; Density functionals; Dinuclear; Mixed-metals; Spin crossings; Triamides; Carbon dioxide; Catalysts; Molybdenum; Tantalum; Transition metals; Niobium; carbon dioxide; coordination compound; metal; niobium; tantalum; vanadium; | |
| dc.title | Tuning the Laplaza-Cummins 3-coordinate M[N(R)Ph] 3 catalyst to activate and cleave CO 2 | |
| dc.type | Journal article | |
| local.bibliographicCitation.issue | 20 | |
| local.bibliographicCitation.lastpage | 5578 | |
| local.bibliographicCitation.startpage | 5569 | |
| local.contributor.affiliation | Brookes, Nigel J, University of Tasmania | |
| local.contributor.affiliation | Ariafard, Alireza, Islamic Azad University | |
| local.contributor.affiliation | Stranger, Robert, College of Physical and Mathematical Sciences, ANU | |
| local.contributor.affiliation | Yates, Brian F, University of Tasmania | |
| local.contributor.authoruid | Stranger, Robert, u8708796 | |
| local.description.embargo | 2037-12-31 | |
| local.description.notes | Imported from ARIES | |
| local.identifier.absfor | 030701 - Quantum Chemistry | |
| local.identifier.absseo | 970103 - Expanding Knowledge in the Chemical Sciences | |
| local.identifier.ariespublication | u4005981xPUB469 | |
| local.identifier.citationvolume | 40 | |
| local.identifier.doi | 10.1039/c1dt10026b | |
| local.identifier.scopusID | 2-s2.0-79955605877 | |
| local.identifier.thomsonID | 000290161900021 | |
| local.type.status | Published Version |
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