Tuning the Laplaza-Cummins 3-coordinate M[N(R)Ph] 3 catalyst to activate and cleave CO 2
Date
2011
Authors
Brookes, Nigel J
Ariafard, Alireza
Stranger, Robert
Yates, Brian F
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
The Laplaza-Cummins catalyst L3Mo (L = N(R)Ar), is experimentally inactive towards carbon dioxide. Previous theoretical analysis identified the cause for this inactivity and suggested that a switch to a d2 transition metal may induce activity towards the
Description
Keywords
Keywords: C-O cleavage; Central metals; Density functionals; Dinuclear; Mixed-metals; Spin crossings; Triamides; Carbon dioxide; Catalysts; Molybdenum; Tantalum; Transition metals; Niobium; carbon dioxide; coordination compound; metal; niobium; tantalum; vanadium;
Citation
Collections
Source
Dalton Transactions
Type
Journal article
Book Title
Entity type
Access Statement
License Rights
Restricted until
2037-12-31
Downloads
File
Description