Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Factors Affecting the Relative and Absolute Rates of β-Scission of Alkoxythiocarbonyl Radicals and Alkoxycarbonyl Radicals

Simple item page
dc.contributor.authorCoote, Michelle
dc.contributor.authorEaston, Christopher
dc.contributor.authorZard, Samir
dc.date.accessioned2015-12-13T23:02:30Z
dc.date.issued2006
dc.date.updated2015-12-12T07:47:38Z
dc.description.abstractHigh-level ab initio calculations demonstrate that alkoxythiocarbonyl radicals (ROC.=S) undergo β-scission significantly faster than alkoxycarbonyl radicals (ROC.=O) despite having similar exothermicities. The relatively low reactivity of the ROC.=O radi
dc.identifier.issn0022-3263
dc.identifier.urihttp://hdl.handle.net/1885/84917
dc.publisherAmerican Chemical Society
dc.sourceJournal of Organic Chemistry
dc.subjectKeywords: Electrons; Reaction kinetics; Stabilization; Alkoxythiocarbonyl radicals; Alkyl radicals; Electron-accepting groups; Exothermicities; Organic compounds; alkyl group; carbonyl derivative; cyanide; radical; thiocarbonyl derivative; unclassified drug; ab ini
dc.titleFactors Affecting the Relative and Absolute Rates of β-Scission of Alkoxythiocarbonyl Radicals and Alkoxycarbonyl Radicals
dc.typeJournal article
local.bibliographicCitation.issue13
local.bibliographicCitation.lastpage4999
local.bibliographicCitation.startpage4996
local.contributor.affiliationCoote, Michelle, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationEaston, Christopher, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationZard, Samir, Ecole Polytechnique
local.contributor.authoruidCoote, Michelle, u4031074
local.contributor.authoruidEaston, Christopher, u9500570
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030505 - Physical Organic Chemistry
local.identifier.absfor030799 - Theoretical and Computational Chemistry not elsewhere classified
local.identifier.ariespublicationMigratedxPub13140
local.identifier.citationvolume71
local.identifier.doi10.1021/jo0607313
local.identifier.scopusID2-s2.0-33745438018
local.type.statusPublished Version

Downloads

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
01_Coote_Factors_Affecting_the_Relative_2006.pdf
Size:
83.24 KB
Format:
Adobe Portable Document Format
Download

Collections

ANU Research Publications

DSpace software copyright © 2002-2026 LYRASIS