Factors Affecting the Relative and Absolute Rates of β-Scission of Alkoxythiocarbonyl Radicals and Alkoxycarbonyl Radicals
Date
Authors
Coote, Michelle
Easton, Christopher
Zard, Samir
Journal Title
Journal ISSN
Volume Title
Publisher
American Chemical Society
Abstract
High-level ab initio calculations demonstrate that alkoxythiocarbonyl radicals (ROC.=S) undergo β-scission significantly faster than alkoxycarbonyl radicals (ROC.=O) despite having similar exothermicities. The relatively low reactivity of the ROC.=O radi
Description
Citation
Collections
Source
Journal of Organic Chemistry
Type
Book Title
Entity type
Access Statement
License Rights
Restricted until
2037-12-31
Downloads
File
Description