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Studies on the mechanism of the reaction between 5�-deoxyadenosylcobinamide and cyanide.

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dc.contributor.authorBrasch, Nicola E
dc.contributor.authorCregan, Andrew
dc.contributor.authorVanselow, Mary
dc.date.accessioned2015-12-13T22:19:37Z
dc.date.available2015-12-13T22:19:37Z
dc.date.issued2002
dc.date.updated2015-12-11T07:49:04Z
dc.description.abstractThe reaction between 5′-deoxyadenosylcobinamide (AdoCbi+OH-) and cyanide (NaCN or tetrabutylammonium cyanide) to form dicyanocobinamide, adenine and 1-cyano-D-erythro-2,3-dihydroxy-4-pentenol has been studied by 1H NMR and UV-visible spectroscopies in a
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/1885/71909
dc.publisherRoyal Society of Chemistry
dc.sourceDalton Transactions
dc.subjectKeywords: Chemical bonds; Cyanides; Negative ions; Nuclear magnetic resonance spectroscopy; Organic solvents; pH effects; Rate constants; Ultraviolet spectroscopy; X ray crystallography; Chemical shifts; Organic compounds
dc.titleStudies on the mechanism of the reaction between 5�-deoxyadenosylcobinamide and cyanide.
dc.typeJournal article
local.bibliographicCitation.lastpage1294
local.bibliographicCitation.startpage1287
local.contributor.affiliationBrasch, Nicola E, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCregan, Andrew, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationVanselow, Mary, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidBrasch, Nicola E, u9808344
local.contributor.authoruidCregan, Andrew, u9507601
local.contributor.authoruidVanselow, Mary, u981613
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030601 - Catalysis and Mechanisms of Reactions
local.identifier.ariespublicationMigratedxPub2945
local.identifier.scopusID2-s2.0-0036010407
local.type.statusPublished Version

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