Cultural advice

The Australian National University acknowledges, celebrates and pays our respects to the Ngunnawal and Ngambri people of the Canberra region and to all First Nations Australians on whose traditional lands we meet and work, and whose cultures are among the oldest continuing cultures in human history.

Aboriginal and Torres Strait Islander peoples are advised that ANU Library collections may include images, names, voices, and other representations of deceased persons.

Material in the collection may contain terms, language or views that reflect the period in which the item was created and may be considered inappropriate today.

Studies on the mechanism of the reaction between 5�-deoxyadenosylcobinamide and cyanide.

Thumbnail Image

Date

2002

Authors

Brasch, Nicola E
Cregan, Andrew
Vanselow, Mary

Journal Title

Journal ISSN

Volume Title

Publisher

Royal Society of Chemistry

Abstract

The reaction between 5′-deoxyadenosylcobinamide (AdoCbi+OH-) and cyanide (NaCN or tetrabutylammonium cyanide) to form dicyanocobinamide, adenine and 1-cyano-D-erythro-2,3-dihydroxy-4-pentenol has been studied by 1H NMR and UV-visible spectroscopies in a

Description

Keywords

Keywords: Chemical bonds; Cyanides; Negative ions; Nuclear magnetic resonance spectroscopy; Organic solvents; pH effects; Rate constants; Ultraviolet spectroscopy; X ray crystallography; Chemical shifts; Organic compounds

Citation

URI

http://hdl.handle.net/1885/71909

Collections

ANU Research Publications

Source

Dalton Transactions

Type

Journal article

Book Title

Entity type

Access Statement

License Rights

DOI

Restricted until

DSpace software copyright © 2002-2026 LYRASIS