Understanding Atom Transfer Radical Polymerization: Effect of Ligand and Initiator Structures on the Equilibrium Constants

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dc.contributor.authorTang, Wei
dc.contributor.authorKwak, Yungwan
dc.contributor.authorBraunecker, Wade
dc.contributor.authorTsarevsky, Nicolay V.
dc.contributor.authorCoote, Michelle
dc.contributor.authorMatyjaszewski, Krzysztof
dc.date.accessioned2015-12-10T22:25:28Z
dc.date.issued2008
dc.date.updated2015-12-09T09:24:45Z
dc.description.abstractEquilibrium constants in Cu-based atom transfer radical polymerization (ATRP) were determined for a wide range of ligands and initiators in acetonitrile at 22°C. The ATRP equilibrium constants obtained vary over 7 orders of magnitude and strongly depend
dc.identifier.issn0002-7863
dc.identifier.urihttp://hdl.handle.net/1885/53497
dc.publisherAmerican Chemical Society
dc.sourceJournal of the American Chemical Society
dc.subjectKeywords: Acetonitrile; Atomic physics; Atoms; Chemical reactions; Copper; Copper alloys; Equilibrium constants; Free radical polymerization; Free radical reactions; Ligands; Monomers; Polymerization; Polymers; Cu-based; Initiator structures; Orders-of-magnitude; A
dc.titleUnderstanding Atom Transfer Radical Polymerization: Effect of Ligand and Initiator Structures on the Equilibrium Constants
dc.typeJournal article
local.bibliographicCitation.issue32
local.bibliographicCitation.lastpage10713
local.bibliographicCitation.startpage10702
local.contributor.affiliationTang, Wei, Carnegie Mellon University
local.contributor.affiliationKwak, Yungwan, Carnegie Mellon University
local.contributor.affiliationBraunecker, Wade, Carnegie Mellon University
local.contributor.affiliationTsarevsky, Nicolay V., Carnegie Mellon University
local.contributor.affiliationCoote, Michelle, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationMatyjaszewski, Krzysztof, Carnegie Mellon University
local.contributor.authoruidCoote, Michelle, u4031074
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.identifier.absfor030799 - Theoretical and Computational Chemistry not elsewhere classified
local.identifier.absfor030305 - Polymerisation Mechanisms
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciences
local.identifier.ariespublicationu4217927xPUB275
local.identifier.citationvolume130
local.identifier.doi10.1021/ja802290a
local.identifier.scopusID2-s2.0-49449097106
local.identifier.thomsonID000258293800057
local.type.statusPublished Version

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