Understanding Atom Transfer Radical Polymerization: Effect of Ligand and Initiator Structures on the Equilibrium Constants
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Tang, Wei
Kwak, Yungwan
Braunecker, Wade
Tsarevsky, Nicolay V.
Coote, Michelle
Matyjaszewski, Krzysztof
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American Chemical Society
Abstract
Equilibrium constants in Cu-based atom transfer radical polymerization (ATRP) were determined for a wide range of ligands and initiators in acetonitrile at 22°C. The ATRP equilibrium constants obtained vary over 7 orders of magnitude and strongly depend
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Journal of the American Chemical Society
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2037-12-31
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