Simple method for the handling of crystals at low temperature: Application to the X-ray structure determination of Bu t 2 P(=NSiMe 3 )NHSiMe 3 and Bu t 2 P(NSiMe 3 ) 2
Date
2002
Authors
Edwards, Alison
Wenger, Eric
Journal Title
Journal ISSN
Volume Title
Publisher
CSIRO Publishing
Abstract
Crystals of the very soluble iminophosphonamide species Bu2tP(=NSiMe3)NHSiMe3 (1) and [But2P(NSiMe3)2]Li·(thf)2 (2) have been obtained and were mounted at dry-ice temperature using a propan-2-ol matrix for X-ray data collection at 100 K. This very simple
Description
Keywords
Keywords: Catalysis; Chelation; Crystal growth; Low temperature engineering; Molecular structure; X ray diffraction; X ray diffraction analysis; Chemical decomposition; Crystal handling; Ligand; X ray structures; Crystal structure
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Source
Australian Journal of Chemistry
Type
Journal article