Efficient Photoinitiating System Based on Diaminoanthraquinone for 3D Printing of Polymer/Carbon Nanotube Nanocomposites under Visible Light
Date
2019-04-01
Authors
Wang, Guannan
Hill, Nicholas
Zhu, Di
Xiao, Pu
Coote, Michelle
Stenzel, Martina H.
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Publisher
ACS Publications
Abstract
This work reports several 1,5-diaminoanthraquinone (1,5-DAAQ)-based visible-light-sensitive photoinitiating systems (PISs), which can efficiently initiate the free radical photopolymerization of (meth)acrylates under green light delivered from light-emitting diode. The PISs contain three components: 1,5-diaminoanthraquinone, an iodonium salt, and aromatic
amines. In one example, polymerization could be efficiently initiated and completed within 10 s with double bond conversions of approximately 80%. The initiating system could also be used in conjunction with reversible addition−fragmentation chain transfer (RAFT) polymerization. Finally, the 1,5-DAAQ/iodonium salt/4-N,N-trimethylaniline PIS could be readily employed
in the 3D printing process of polymer/carbon nanotube nanocomposites.
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Keywords
3D printing, photopolymerization, carbon nanoparticles, three-component photoinitiating systems, green light, LED
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Source
ACS Applied Polymer Materials
Type
Journal article
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2037-12-31
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