Efficient Photoinitiating System Based on Diaminoanthraquinone for 3D Printing of Polymer/Carbon Nanotube Nanocomposites under Visible Light

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dc.contributor.authorWang, Guannan
dc.contributor.authorHill, Nicholas
dc.contributor.authorZhu, Di
dc.contributor.authorXiao, Pu
dc.contributor.authorCoote, Michelle
dc.contributor.authorStenzel, Martina H.
dc.date.accessioned2020-07-07T02:22:33Z
dc.date.issued2019-04-01
dc.date.updated2020-06-23T00:54:37Z
dc.description.abstractThis work reports several 1,5-diaminoanthraquinone (1,5-DAAQ)-based visible-light-sensitive photoinitiating systems (PISs), which can efficiently initiate the free radical photopolymerization of (meth)acrylates under green light delivered from light-emitting diode. The PISs contain three components: 1,5-diaminoanthraquinone, an iodonium salt, and aromatic amines. In one example, polymerization could be efficiently initiated and completed within 10 s with double bond conversions of approximately 80%. The initiating system could also be used in conjunction with reversible addition−fragmentation chain transfer (RAFT) polymerization. Finally, the 1,5-DAAQ/iodonium salt/4-N,N-trimethylaniline PIS could be readily employed in the 3D printing process of polymer/carbon nanotube nanocomposites.en_AU
dc.description.sponsorshipG.W. acknowledges the Chinese Scholarship Council (CSC) for scholarship support. P.X. acknowledges funding from the Australian Research Council Future Fellowship (FT170100301). M.L.C. gratefully acknowledges a Georgina Sweet ARC Laureate Fellowship (FL170100041) and generous allocations of supercomputing time on the National Facility of the Australian National Computational Infrastructure.en_AU
dc.format.mimetypeapplication/pdfen_AU
dc.identifier.issn2637-6105en_AU
dc.identifier.urihttp://hdl.handle.net/1885/205885
dc.language.isoen_AUen_AU
dc.publisherACS Publicationsen_AU
dc.relationhttp://purl.org/au-research/grants/arc/FT170100301en_AU
dc.relationhttp://purl.org/au-research/grants/arc/FL170100041en_AU
dc.rights© 2019 American Chemical Societyen_AU
dc.sourceACS Applied Polymer Materialsen_AU
dc.subject3D printingen_AU
dc.subjectphotopolymerizationen_AU
dc.subjectcarbon nanoparticlesen_AU
dc.subjectthree-component photoinitiating systemsen_AU
dc.subjectgreen lighten_AU
dc.subjectLEDen_AU
dc.titleEfficient Photoinitiating System Based on Diaminoanthraquinone for 3D Printing of Polymer/Carbon Nanotube Nanocomposites under Visible Lighten_AU
dc.typeJournal articleen_AU
dcterms.dateAccepted2019-04-01
local.bibliographicCitation.issue5en_AU
local.bibliographicCitation.lastpage1135en_AU
local.bibliographicCitation.startpage1129en_AU
local.contributor.affiliationWang, Guannan, University of New South Walesen_AU
local.contributor.affiliationHill, Nicholas, College of Science, ANUen_AU
local.contributor.affiliationZhu, Di, College of Science, ANUen_AU
local.contributor.affiliationXiao, Pu, College of Science, ANUen_AU
local.contributor.affiliationCoote, Michelle, College of Science, ANUen_AU
local.contributor.affiliationStenzel, Martina H., University of New South Walesen_AU
local.contributor.authoremailu4031074@anu.edu.auen_AU
local.contributor.authoruidHill, Nicholas, u6132601en_AU
local.contributor.authoruidZhu, Di, t1813en_AU
local.contributor.authoruidXiao, Pu, u1053596en_AU
local.contributor.authoruidCoote, Michelle, u4031074en_AU
local.description.embargo2037-12-31
local.description.notesImported from ARIESen_AU
local.identifier.absfor030305 - Polymerisation Mechanismsen_AU
local.identifier.absseo970103 - Expanding Knowledge in the Chemical Sciencesen_AU
local.identifier.ariespublicationu3102795xPUB4910en_AU
local.identifier.citationvolume1en_AU
local.identifier.doi10.1021/acsapm.9b00140en_AU
local.identifier.thomsonIDWOS:000476966900025
local.identifier.uidSubmittedByu3102795en_AU
local.publisher.urlhttps://pubs.acs.org/en_AU
local.type.statusPublished Versionen_AU

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