Thiocarbonylphosphorane and arsorane ligands
| dc.contributor.author | Burt, Liam | |
| dc.contributor.author | Hill, Anthony | |
| dc.contributor.author | Jones, Stephanie | |
| dc.date.accessioned | 2023-01-03T05:28:03Z | |
| dc.date.issued | 2022-10-04 | |
| dc.description.abstract | Independently unstable thiocarbonylphosphorane or arsorane ligands SCAR3 (A = P, As) are observed in the salts [W(η2-C,S-SCAR3)(CO)2(Tp*)]PF6 [AR3 = PCy3, PMenPh3-n: n = 0, 1, 2, AsMePh2; Tp* = tris(dimethylpyrazolyl)borate] which arise from the reactions of phosphonio- or arsoniocarbynes [W(≡CAR3)(CO)2(Tp*)]+ with sulfur. | en_AU |
| dc.description.sponsorship | We gratefully acknowledge the Australian Research Council (DP190100723 and DP200101222) for funding. | en_AU |
| dc.format.mimetype | application/pdf | en_AU |
| dc.identifier.issn | 1359-7345 | en_AU |
| dc.identifier.uri | http://hdl.handle.net/1885/282555 | |
| dc.language.iso | en_AU | en_AU |
| dc.provenance | https://v2.sherpa.ac.uk/id/publication/18003..."The Accepted Version can be archived in a Non-Commercial Institutional Repository. 12 months embargo" from SHERPA/RoMEO site (as at 03/01/2023). | en_AU |
| dc.publisher | Royal Society of Chemistry | en_AU |
| dc.relation | http://purl.org/au-research/grants/arc/DP190100723 | en_AU |
| dc.relation | http://purl.org/au-research/grants/arc/DP200101222 | en_AU |
| dc.rights | © 2022 Royal Society of Chemistry | en_AU |
| dc.source | Chemical communications | en_AU |
| dc.subject | crystallography, x-ray | en_AU |
| dc.subject | ligands | en_AU |
| dc.subject | models, molecular | en_AU |
| dc.subject | sulfur | en_AU |
| dc.subject | borates | en_AU |
| dc.subject | salts | en_AU |
| dc.title | Thiocarbonylphosphorane and arsorane ligands | en_AU |
| dc.type | Journal article | en_AU |
| dcterms.accessRights | Open Access | en_AU |
| local.bibliographicCitation.issue | 79 | en_AU |
| local.bibliographicCitation.lastpage | 11094 | en_AU |
| local.bibliographicCitation.startpage | 11091 | en_AU |
| local.contributor.affiliation | Bert, L., College of Science, The Australian National University | en_AU |
| local.contributor.affiliation | Hill, A., College of Science, The Australian National University | en_AU |
| local.contributor.authoruid | u4030185 | en_AU |
| local.description.embargo | 2023-10-04 | |
| local.identifier.citationvolume | 58 | en_AU |
| local.identifier.doi | 10.1039/d2cc03747e | en_AU |
| local.identifier.essn | 1364-548X | en_AU |
| local.publisher.url | https://pubs.rsc.org/ | en_AU |
| local.type.status | Accepted Version | en_AU |