Thiocarbonylphosphorane and arsorane ligands
Date
2022-10-04
Authors
Burt, Liam
Hill, Anthony
Jones, Stephanie
Journal Title
Journal ISSN
Volume Title
Publisher
Royal Society of Chemistry
Abstract
Independently unstable thiocarbonylphosphorane or arsorane ligands SCAR3 (A = P, As) are observed in the salts [W(η2-C,S-SCAR3)(CO)2(Tp*)]PF6 [AR3 = PCy3, PMenPh3-n: n = 0, 1, 2, AsMePh2; Tp* = tris(dimethylpyrazolyl)borate] which arise from the reactions of phosphonio- or arsoniocarbynes [W(≡CAR3)(CO)2(Tp*)]+ with sulfur.
Description
Keywords
crystallography, x-ray, ligands, models, molecular, sulfur, borates, salts
Citation
Collections
Source
Chemical communications
Type
Journal article
Book Title
Entity type
Access Statement
Open Access
License Rights
Restricted until
2023-10-04
Downloads
File
Description