The mechanism of Bu 3 SnH-mediated homolytic aromatic substitution
Date
2004
Authors
Beckwith, Athelstan (Athel)
Bowry, Vincent W
Bowman, W Russell
Mann, Emma
Parr, Jonathan
Storey, John W
Journal Title
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Volume Title
Publisher
Wiley-VCH Verlag GMBH
Abstract
The fate of intermediate π radicals is crucial in Bu 3SnH-mediated cyclization by homolytic aromatic substitution, for example, of bromo compound 1 via radical 2 to give oxindole 3 (AIBN = azobisisobutyronitrile). The results indicate that the mechanism
Description
Keywords
Keywords: Radical reactions; Bromine compounds; Free radicals; Hydrogen; Solvents; Substitution reactions; Aromatic compounds; aromatic compound; azobisisobutyronitrile; hydrogen; oxindole; polycyclic aromatic hydrocarbon; radical; solvent; tin; unclassified drug; Azo compounds; Cyclization; Radical reactions; Radicals; Reaction mechanisms
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Source
Angewandte Chemie International Edition
Type
Journal article
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2037-12-31