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The reversible and stereoselective N- to C-bonded rearrangement of tris(2-pyridylmethyl)-1,4,7-triazacyclononanecobalt(III)

Jackson, William Gregory; McKeon, Josephine A; Hockless, David; Willis, Anthony

Description

The hexaaminecobalt(III) complex [Co(tmptacn)]3+ (tmptacn = 1,4,7-tris(2′-pyridylmethyl)-1,4,7-triazacyclononane) undergoes a novel base-catalyzed N- to C-bonded rearrangement in which a tacn nitrogen is displaced by the α-carbon which deprotonates and

CollectionsANU Research Publications
Date published: 2006
Type: Journal article
URI: http://hdl.handle.net/1885/85223
Source: Inorganic Chemistry
DOI: 10.1021/ic051997f

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