The reversible and stereoselective N- to C-bonded rearrangement of tris(2-pyridylmethyl)-1,4,7-triazacyclononanecobalt(III)
Date
2006
Authors
Jackson, William Gregory
McKeon, Josephine A
Hockless, David
Willis, Anthony
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Volume Title
Publisher
American Chemical Society
Abstract
The hexaaminecobalt(III) complex [Co(tmptacn)]3+ (tmptacn = 1,4,7-tris(2′-pyridylmethyl)-1,4,7-triazacyclononane) undergoes a novel base-catalyzed N- to C-bonded rearrangement in which a tacn nitrogen is displaced by the α-carbon which deprotonates and
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Keywords
Keywords: carbon; nitrogen; organometallic compound; tris(2 pyridylmethyl) 1,4,7 triazacyclononanecobalt(III); tris(2-pyridylmethyl)-1,4,7-triazacyclononanecobalt(III); article; catalysis; chemical structure; chemistry; conformation; kinetics; methodology; nuclear
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Inorganic Chemistry
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Journal article
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2037-12-31
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