Aminocyclodextrins to facilitate the deprotonation of 4- tert -butyl-α-nitrotoluene
Date
2005
Authors
Barr, Lorna
Easton, Christopher
Lee, Kitty
Lincoln, Stephen F
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Publisher
Royal Society of Chemistry
Abstract
6A-Amino-6A-deoxy-β-cyclodextrin enhances the rate of the deprotonation of 4-terf-butyl-α-nitrotoluene. The rate constants for reaction of the cyclodextrin-bound species, kinc = 4 × 10-3, 9 × 10-3 and 19 × 10 -3 s-1, at pH 6.0, 6.5 and 7.0, respectiv
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Keywords: Acceleration; Amines; Complexation; Deuterium; Ketones; Oligomers; pH effects; Toluene; 4-terf-butyl-?-nitrotoluene; Aminocyclodextrins; Hydrogen-deuterium exchange; Rate acceleration; Reaction kinetics; cyclodextrin; drug derivative; toluene; article; ch
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Organic and Biomolecular Chemistry
Type
Journal article
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2037-12-31
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