Aminocyclodextrins to facilitate the deprotonation of 4- tert -butyl-α-nitrotoluene

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dc.contributor.authorBarr, Lorna
dc.contributor.authorEaston, Christopher
dc.contributor.authorLee, Kitty
dc.contributor.authorLincoln, Stephen F
dc.date.accessioned2015-12-13T22:53:50Z
dc.date.issued2005
dc.date.updated2015-12-11T11:00:07Z
dc.description.abstract6A-Amino-6A-deoxy-β-cyclodextrin enhances the rate of the deprotonation of 4-terf-butyl-α-nitrotoluene. The rate constants for reaction of the cyclodextrin-bound species, kinc = 4 × 10-3, 9 × 10-3 and 19 × 10 -3 s-1, at pH 6.0, 6.5 and 7.0, respectiv
dc.identifier.issn1477-0520
dc.identifier.urihttp://hdl.handle.net/1885/81990
dc.publisherRoyal Society of Chemistry
dc.sourceOrganic and Biomolecular Chemistry
dc.subjectKeywords: Acceleration; Amines; Complexation; Deuterium; Ketones; Oligomers; pH effects; Toluene; 4-terf-butyl-?-nitrotoluene; Aminocyclodextrins; Hydrogen-deuterium exchange; Rate acceleration; Reaction kinetics; cyclodextrin; drug derivative; toluene; article; ch
dc.titleAminocyclodextrins to facilitate the deprotonation of 4- tert -butyl-α-nitrotoluene
dc.typeJournal article
local.bibliographicCitation.issue16
local.bibliographicCitation.lastpage2993
local.bibliographicCitation.startpage2990
local.contributor.affiliationBarr, Lorna, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationEaston, Christopher, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLee, Kitty, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationLincoln, Stephen F, University of Adelaide
local.contributor.authoremailu9500570@anu.edu.au
local.contributor.authoruidBarr, Lorna, u4013429
local.contributor.authoruidEaston, Christopher, u9500570
local.contributor.authoruidLee, Kitty, u4000283
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor030302 - Nanochemistry and Supramolecular Chemistry
local.identifier.ariespublicationMigratedxPub10292
local.identifier.citationvolume3
local.identifier.doi10.1039/b506187c
local.identifier.scopusID2-s2.0-24144454152
local.identifier.uidSubmittedByMigrated
local.type.statusPublished Version

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