Poly(azolyl) chelate chemistry 14.[1] κ 2 - S,S vs κ 3 -H, S,S -H 2 B(mt) 2 (mt = methimazolyl)borate coordination in the complex [W(CO){H 2 B(mt) 2 } 2 ]
Date
2005
Authors
Abernethy, Robyn
Hill, Anthony
Neumann, Horst
Willis, Anthony
Journal Title
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Publisher
Elsevier
Abstract
The reactions of [M(≡CC6H2Me 3-2,4,6)X(CO)2(L)2] (M = Mo, W; X = Cl, Br; L = pyridine, 3,5-dimethylpyrazole) with Na[H2B(mt)2] (mt = methimazolyl) are metal dependent, providing either the alkylidyne complex [Mo(≡CC6H2Me3-2,4, 6)(CO) 2{κ3-H,S,S′-H2
Description
Keywords
Keywords: alkyne derivative; boric acid; boron; chelate; hydrogen; ligand; metal; molybdenum complex; tungsten derivative; article; chemistry; molecular interaction; synthesis Agostic coordination; Alkylidyne; Borate; Carbyne; Molybdenum; Tungsten
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Source
Inorganica Chimica Acta
Type
Journal article
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2037-12-31