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Poly(azolyl) chelate chemistry 14.[1] κ 2 - S,S vs κ 3 -H, S,S -H 2 B(mt) 2 (mt = methimazolyl)borate coordination in the complex [W(CO){H 2 B(mt) 2 } 2 ]

Abernethy, Robyn; Hill, Anthony; Neumann, Horst; Willis, Anthony

Description

The reactions of [M(≡CC6H2Me 3-2,4,6)X(CO)2(L)2] (M = Mo, W; X = Cl, Br; L = pyridine, 3,5-dimethylpyrazole) with Na[H2B(mt)2] (mt = methimazolyl) are metal dependent, providing either the alkylidyne complex [Mo(≡CC6H2Me3-2,4, 6)(CO) 2{κ3-H,S,S′-H2

CollectionsANU Research Publications
Date published: 2005
Type: Journal article
URI: http://hdl.handle.net/1885/76120
Source: Inorganica Chimica Acta
DOI: 10.1016/j.ica.2004.07.061

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