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Poly(azolyl) chelate chemistry 14.[1] κ 2 - S,S vs κ 3 -H, S,S -H 2 B(mt) 2 (mt = methimazolyl)borate coordination in the complex [W(CO){H 2 B(mt) 2 } 2 ]

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dc.contributor.authorAbernethy, Robyn
dc.contributor.authorHill, Anthony
dc.contributor.authorNeumann, Horst
dc.contributor.authorWillis, Anthony
dc.date.accessioned2015-12-13T22:34:27Z
dc.date.issued2005
dc.date.updated2015-12-11T09:21:10Z
dc.description.abstractThe reactions of [M(≡CC6H2Me 3-2,4,6)X(CO)2(L)2] (M = Mo, W; X = Cl, Br; L = pyridine, 3,5-dimethylpyrazole) with Na[H2B(mt)2] (mt = methimazolyl) are metal dependent, providing either the alkylidyne complex [Mo(≡CC6H2Me3-2,4, 6)(CO) 2{κ3-H,S,S′-H2
dc.identifier.issn0020-1693
dc.identifier.urihttp://hdl.handle.net/1885/76120
dc.publisherElsevier
dc.sourceInorganica Chimica Acta
dc.subjectKeywords: alkyne derivative; boric acid; boron; chelate; hydrogen; ligand; metal; molybdenum complex; tungsten derivative; article; chemistry; molecular interaction; synthesis Agostic coordination; Alkylidyne; Borate; Carbyne; Molybdenum; Tungsten
dc.titlePoly(azolyl) chelate chemistry 14.[1] κ 2 - S,S vs κ 3 -H, S,S -H 2 B(mt) 2 (mt = methimazolyl)borate coordination in the complex [W(CO){H 2 B(mt) 2 } 2 ]
dc.typeJournal article
local.bibliographicCitation.issue5
local.bibliographicCitation.lastpage1613
local.bibliographicCitation.startpage1605
local.contributor.affiliationAbernethy, Robyn, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationHill, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationNeumann, Horst, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationWillis, Anthony, College of Physical and Mathematical Sciences, ANU
local.contributor.authoruidAbernethy, Robyn, u2540805
local.contributor.authoruidHill, Anthony, u4030185
local.contributor.authoruidNeumann, Horst, u7500731
local.contributor.authoruidWillis, Anthony, u8512028
local.description.embargo2037-12-31
local.description.notesImported from ARIES
local.description.refereedYes
local.identifier.absfor039904 - Organometallic Chemistry
local.identifier.ariespublicationMigratedxPub5011
local.identifier.citationvolume358
local.identifier.doi10.1016/j.ica.2004.07.061
local.identifier.scopusID2-s2.0-14644427164
local.type.statusPublished Version

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