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Studies on the mechanism of the reaction between 5�-deoxyadenosylcobinamide and cyanide.

Brasch, Nicola E; Cregan, Andrew; Vanselow, Mary

Description

The reaction between 5′-deoxyadenosylcobinamide (AdoCbi+OH-) and cyanide (NaCN or tetrabutylammonium cyanide) to form dicyanocobinamide, adenine and 1-cyano-D-erythro-2,3-dihydroxy-4-pentenol has been studied by 1H NMR and UV-visible spectroscopies in a

dc.contributor.authorBrasch, Nicola E
dc.contributor.authorCregan, Andrew
dc.contributor.authorVanselow, Mary
dc.date.accessioned2015-12-13T22:19:37Z
dc.date.available2015-12-13T22:19:37Z
dc.identifier.issn1477-9226
dc.identifier.urihttp://hdl.handle.net/1885/71909
dc.description.abstractThe reaction between 5′-deoxyadenosylcobinamide (AdoCbi+OH-) and cyanide (NaCN or tetrabutylammonium cyanide) to form dicyanocobinamide, adenine and 1-cyano-D-erythro-2,3-dihydroxy-4-pentenol has been studied by 1H NMR and UV-visible spectroscopies in a
dc.publisherRoyal Society of Chemistry
dc.sourceDalton Transactions
dc.subjectKeywords: Chemical bonds; Cyanides; Negative ions; Nuclear magnetic resonance spectroscopy; Organic solvents; pH effects; Rate constants; Ultraviolet spectroscopy; X ray crystallography; Chemical shifts; Organic compounds
dc.titleStudies on the mechanism of the reaction between 5�-deoxyadenosylcobinamide and cyanide.
dc.typeJournal article
local.description.notesImported from ARIES
local.description.refereedYes
dc.date.issued2002
local.identifier.absfor030601 - Catalysis and Mechanisms of Reactions
local.identifier.ariespublicationMigratedxPub2945
local.type.statusPublished Version
local.contributor.affiliationBrasch, Nicola E, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationCregan, Andrew, College of Physical and Mathematical Sciences, ANU
local.contributor.affiliationVanselow, Mary, College of Physical and Mathematical Sciences, ANU
local.bibliographicCitation.startpage1287
local.bibliographicCitation.lastpage1294
dc.date.updated2015-12-11T07:49:04Z
local.identifier.scopusID2-s2.0-0036010407
CollectionsANU Research Publications

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